A Pythagorean triangle can never have a 22.5 degree angle, since tan(22.5) is 1-sqrt(2) which is irrational, however a 5,12,13 triangle comes very close. (It isn’t surpassed in accuracy until it is marginally improved in a triangle whose shortest side is 3648).
If three triangles with sides in the ratio 5,12,13 are placed with their smallest angles together as shown, what Pythagorean triangle has the necessary angle to complete the right angle?